The impact of metal coordination on the assembly of bis(indolyl)methane-naphthalene-diimide amphiphiles

dc.contributor.author	Bayindir, S. and Lee, K.S. and Saracoglu, N. and Parquette, J.R.
dc.date.accessioned	2021-04-08T12:06:10Z
dc.date.available	2021-04-08T12:06:10Z
dc.date.issued	2020
dc.identifier	10.1039/d0dt02732d
dc.identifier.issn	14779226
dc.identifier.uri	https://www.scopus.com/inward/record.uri?eid=2-s2.0-85092945458&doi=10.1039%2fd0dt02732d&partnerID=40&md5=7077ffd3b046f8b8c175d64e0ea87607
dc.identifier.uri	http://acikerisim.bingol.edu.tr/handle/20.500.12898/3858
dc.description.abstract	The self-assembly and coordination of amphiphiles comprised of naphthalenediimide (NDI) and bis(indolyl)methane (BIM) chromophores were investigated as a function of pH and metal. As observed by TEM, SEM and AFM imaging, the self-assembly of NDI-BIM 1 produced irregular nanostructures at neutral pH in CH3CN-H2O (1 : 1); whereas, well-defined nanotubes were observed at pH 2. Conversely, Fmoc-protected, NDI-BIM 2 formed nanotubes at neutral pH and nonspecific aggregates at pH 2. Upon coordination of Cu2+ ions to the bis(indoyl)methane moiety, a reorganization from nanotubes to vesicular structures was observed. This journal is © The Royal Society of Chemistry.
dc.language.iso	English
dc.source	Dalton Transactions
dc.title	The impact of metal coordination on the assembly of bis(indolyl)methane-naphthalene-diimide amphiphiles

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