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Innovative hydrogen release from sodium borohydride hydrolysis using biocatalyst-like Fe2O3 nanoparticles impregnated on Bacillus simplex bacteria

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2021
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Duman, S. and Kaya, B. and Caf, F. and Enez, B. and Fincan, S.A.
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For the first time in this innovative study, microorganisms such as Bacillus simplex bacteria, mostly used in biological activity studies, are used as a bio-supporter agent of iron to release hydrogen from sodium borohydride hydrolysis at 25.0 ± 0.1 °C. The goal is to investigate thoroughly sodium borohydride hydrolysis catalyzed by Fe2O3 nanoparticles impregnated on microorganism such as Bacillus simplex (BS) bacteria (Fe2O3@BS NPs) known with strong antibacterial properties, which makes innovative them a candidate for hydrolysis reaction. This study was focused on the preparation, identification, and catalytic use of biocatalyst-like Fe2O3@BS NPs for hydrogen release from the sodium borohydride hydrolysis at 25.0 ± 0.1 °C. The characterization results made after and before hydrolysis reaction using by SEM/SEM-EDX, FT-IR, XRD, UV–vis, XPS, DLS, ELS Zeta potential, ESR, and TEM techniques reveal the formation of highly active, stable, durable, and long-lived biocatalysts-like Fe2O3@BS NPs. © 2021 Hydrogen Energy Publications LLC
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-85101812028&doi=10.1016%2fj.ijhydene.2021.02.028&partnerID=40&md5=87224e4fcea94ba0e52ba976c2f838d1
http://acikerisim.bingol.edu.tr/handle/20.500.12898/3801
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