Synthesis of N-Alkylated Indolines and Indoles from Indoline and Aliphatic Ketones
Date
2015Author
Bayindir, S. and Erdogan, E. and Kilic, H. and Aydin, O. and Saracoglu, N.
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A survey of redox aminations of indoline with aliphatic ketones using bismuth nitrate as catalyst is described. A reaction of an equivalent amount of indoline and aliphatic cyclic and acyclic ketones provides a mixture of excessive alkylated indole derivatives over typically redox isomerization and reductive alkylation pathways while using of the five equivalent of indoline provides N-alkylated indolines as a reductive alkylation product. The desired N-alkyl indoles from the oxidation of N-alkyl indolines were obtained in excellent yields. © 2015 HeteroCorporation.
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-84942552771&doi=10.1002%2fjhet.2337&partnerID=40&md5=5379b24a0af530e5b921968472d0f8cchttp://acikerisim.bingol.edu.tr/handle/20.500.12898/4730
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